As it turns out, Astatine is is the rarest of all naturally occurring element. According to Wikipedia, there is less than an ounce in the entire Earth's crust. I think that means it is safe to assume we don't have to worry about it showing up in printed circuit boards!
Since At is extremely radioactive, I highly recommend avoiding it if you see some on the sidewalk but don't worry too much about it in your halogen-free testing.